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Phosphinate flame retardant system for reinforced polyamide 6 and polyamide 66

Atrajet™ 300 P

Atrajet 300 P is a non-halogenated flame retardant based on organic phosphinates. The product achieves its flame-retardant effect through intumescence and gas phase activity. The thermoplastic polymer with Atrajet 300 P foams and crosslinks on exposure to flame and forms a stable char at the surface acting as a barrier. The protective layer provides a heat-insulating effect, reduces oxygen access and prevents dripping of molten polymer. Atrajet 300 P is a white powder.

Benefits
  • UL 94 V-0 rating down to 0.4 mm thickness 
  • CTI up to 600 V 
  • Low smoke density
  • For all colors
  • The flame retarded polyamide compounds exhibit sufficient mechanical properties for most applications
Safety

For regulatory details such as the classification and labelling as dangerous substances or goods please refer to our corresponding Material Safety Data Sheet. For disposal in accordance with the regulations the product should be treated as special waste and taken to a suitable incineration plant.

Specifications

 

Characteristics

Unit

Target Value

DS¹)

 

Test Method 

Phosphorus 

%(w/w)  

18.5 - 19.9  

Photometry after oxidizing dissolution; (11/17) or wavelength dispersive X-ray fluorescence spectrometry; (11/23)  

Water / Moisture 

%(by wt.)  

max. 0.5  

Karl-Fischer titration; (11/21)  

¹) Delivery specification: The product is monitored on a regular basis to ensure that it adheres to the specified values. Test methods: Clariant method numbers 11/xx in brackets.

Applications

Atrajet 300 P was developed especially for use in polyamides. It is suited for both glass-fibre-reinforced and unreinforced grades. The flame retarded polyamide compounds exhibit very good physical and electrical properties.

To achieve higher tensile and impact properties we recommend Exolit OP 1312, for higher thermal stability and the use in hot and humid atmospheres we recommend Exolit OP 1400.

Formulation

In glass-fibre-reinforced polyamide 6 or 6.6, a dosage of 15 to 20 % (by wt.) Atrajet 300 P is usually sufficient to obtain the UL 94 V-0 classification for electrical components (at 1.6 as well as 0.8 mm thickness). Subject to the polymer grade, processing conditions and glass- fibre reinforcement the dosage of the flame retardant may vary.

Processing

Before incorporating Atrajet 300 P, it is important to predry the polyamide as usual. If possible, the resulting moisture content should be below 0.1 % (by wt.). Predrying of Atrajet 300 P is not necessary. However, predrying (e.g. 4 h at 120 °C) is recommended, if even very low moisture contents must be avoided.

The mixing and processing methods customary in powder processing of polymers can be used with Atrajet 300 P. The VDI Guideline 2263 “Prevention of dust fires and dust explosions” or the relevant national regulations must be observed.

The optimum conditions for incorporating should be determined in each individual case. Care must be taken to ensure homogeneous dispersion of all components. The temperature of the polymer melt should not exceed 320 °C.

Packaging and Handling

Delivery form
White powder

Packaging
Atrajet 300 P is delivered in 20 kg paper bags with PE inliner or 500 kg big bags.

Storage

The product should be stored in a dry place at room temperature.

Minimum shelf life is 12 months from the date of shipping when stored according to the said conditions.

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