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Highly stable phosphinate flame retardant system for polyamides

Atrajet™ 400 P

Atrajet 400 P is a non-halogenated flame retardant based on organic phosphinates. The product achieves its flame-retardant effect through a combined gas phase and condensed phase mode of action.  The thermoplastic polymer with Atrajet 400 P forms on exposure to flame a stable char at the surface acting as a barrier. The protective layer provides a heat-insulating effect, reduces oxygen access and prevents dripping of molten polymer. Atrajet 400 P is a white powder.

Benefits
  • UL 94 V-0 rating down to 0.4 mm thickness 
  • CTI up to 600 V 
  • Low smoke density
  • For all colors
  • Good mechanical properties
  • Suitable for all kind of polyamides
  • Suitable for hot and humid environments
Safety

For regulatory details such as the classification and labelling as dangerous substances or goods please refer to our corresponding Material Safety Data Sheet. For disposal in accordance with the regulations the product should be treated as special waste and taken to a suitable incineration plant.

Technical Data

Characteristics

Unit

Target Value

DS¹)

 

Test Method 

Phosphorus 

%(w/w)  

22.0 -26.2  

Photometry after oxidizing dissolution; (11/17) or wavelength dispersive X-ray fluorescence spectrometry; (11/23)  

Water / Moisture 

%(by wt.)  

max. 0.8

Karl-Fischer titration; (11/21)  

¹) Delivery specification: The product is monitored on a regular basis to ensure that it adheres to the specified values. Test methods: Clariant method numbers 11/xx in brackets.

Applications

Atrajet 400 P was developed especially for use in polyamides. It is suited for both glass-fibre-reinforced and unreinforced grades and for PA 6, PA 66 and for high temperature polyamides. The flame retarded polyamide compounds exhibit very good physical and electrical properties. 

Atrajet 400 P shows beginning weight loss above 200°C (TGA, approx. 3%). For a better thermal stability, we rerommend Exolit OP 1400.

Formulation

In glass-fibre-reinforced polyamide 6 or 6.6, a dosage of about 20 % (by wt.) Atrajet 400 P is usually sufficient to obtain the UL 94 V-0 classification for electrical components (at 1.6 as well as 0.8 mm and 0.4 mm thickness). Subject to the polymer grade, processing conditions and glass- fibre reinforcement the dosage of the flame retardant may vary.

Processing

Before incorporating Atrajet 400 P, it is important to predry the polyamide as usual. If possible, the resulting moisture content should be below 0.1 % (by wt.). Predrying of Atrajet 400 P is not necessary. However, predrying (e.g. 4 h at 120 °C) is recommended, if even very low moisture contents must be avoided.

The mixing and processing methods customary in powder processing of polymers can be used with Atrajet 400 P. The VDI Guideline 2263 “Prevention of dust fires and dust explosions” or the relevant national regulations must be observed.

The optimum conditions for incorporating should be determined in each individual case. Care must be taken to ensure homogeneous dispersion of all components. The temperature of the polymer melt should not exceed 340 °C.

Packaging and Handling

Delivery form
White powder

Packaging
Atrajet 400 P is delivered in 20 kg paper bags with PE inliner or 500 kg big bags.

Storage

The product should be stored in a dry place at room temperature.

Minimum shelf life is 12 months from the date of shipping when stored according to the said conditions.

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